You need to adjust the settings in the new profile. In Settings/General Options - Request confirmation for every critical operation must be unticked to allow automatic unattended betting. The option above that is better unticked also.
In Monitoring Options - Scheduled Market Search, make sure that the appropriate Market Locator template is in the box ie. one that finds Win markets.
The profile is not a betting trigger, you need to load a .mft file for anything to happen. I don't know what you mean by default trigger. Perhaps a quick read of the getting started section of the manual might help?